I tested this question two different ways:
First: I ran between all Piles of Bones clicking 100 times and acquiring 30 Crude Horn of Bone in this run. This method allows the user a 30% success rate at getting a horn. Now with this being said, even with the odds of success being around 30%, you have a higher chance at acquiring more bones in a shorter time frame.
Second: I clicked a single Pile of Bones 50 times consecutively. I acquired 17 Crude Horn of Bone during this test. This is approximately a 34% success rate.
All in all, it appears as though there is a higher chance to spawn a Guzzlemaw (between 66-70% chance) versus Collecting a Crude Horn of Bone (between 30-34% chance).
Below are videos from each test if you are interested in how I came to have these numbers. Both videos have been sped up due to the time consuming manor of these tests.
First test:
https://youtu.be/Zte--aOGTsc
Second Test:
https://youtu.be/Tde9bYkaXgA