Here’s the list of pickupable “skull” collectibles items. If I forget something, please comment so I can update my answer later:
Skull (item) – common “human skull”; dropped from several creatures, Amazons being one of the easiest sources (also drops from Valkyries, Vampires, Necromancers, etc.).
Black Skull (item) – dropped from Hellspawn and Infernalist.
Diabolic Skull – dropped from Brachiodemon, The Brainstealer and Rotrender.
Golden Skull – dropped from Tentugly's Head and Rotrender.
Megalomania’s Skull – dropped from Goshnar’s Megalomania.
Werebadger Skull – dropped from Werebadger and Sharpclaw.
Werebear Skull – dropped from Werebear and Shadowpelt.
Skull Fetish – dropped from all kinds of Ogres.
Skull Shatterer – dropped from Lost Exile and Lost Husher.
Stonerefiner’s Skull – dropped from Stonerefiner.
Mysterious Voodoo Skull – dropped from Enlightened of the Cult, Nightmare, Vampire Bride, etc.
Cavebear Skull – dropped from Undead Cavebear.
Quest Skulls:
Green Skull, Black Skull, White Skull, Red Skull, Orange Skull and Yellow Skull – reward from 25 Years of Tibia Quest. The same quest also gives Bridal Black Skull.
Blood Skull – Obtained in one of the hidden parts of Vengoth after delivering 100 Vampire Lord Tokens to Storkus in the Vampire Hunter Quest.
Vial with a Skull Cork – Obtained/used during Feaster of Souls Quest.
Orc Skull – Obtained/used during The Dream Courts Quest.
Troll Skull – Obtained/used during The Dream Courts Quest.
Minotaur Skull – Obtained/used during The Dream Courts Quest.
Drowned Seaman’s Skull – Obtained/used during Twenty Miles Beneath the Sea Quest.
Skull of Ratha – Obtained/used during The Explorer Society Quest.
Skull of a Caveman – Obtained/used during Unnatural Selection Quest.
Omrabas’ Talking Skull – Obtained/used during The Gravedigger of Drefia Quest.
Tibia Store Skull Decorations (Decoration Kit for houses):
Demon Skull – Store decoration.
Golden Demon Skull – Store decoration.
Sabretooth Skull – Store decoration.
Addon/Mount items:
Demon Skull – loot from Arbaziloth; used for the Fiend Slayer outfit addon (addon 2).
The Skull of a Beast – loot from Goshnar’s Malice, used for the Revenant outfit addon (addon 2).
That's it, I hope this list helps on your objective of decorating your house. Have fun!
The previous answer left a few skulls aside, here is a list to complement the previous one
• Skull Helmet
Dropped by: Beholders, Elder Beholders, Undead Dragons, etc.
While wearable, it is still a literal skull-based item often overlooked in lists like this.
• Bonebeast Skull
Dropped by: Bonebeasts
Separate item from generic “skull” and used mainly as loot/deco.
• Dragon Skull
Dropped by: Undead Dragons
Used mainly as decoration and creature product.
• Mutated Bat Skull
Dropped by: Mutated Bats
Distinct item, not interchangeable with normal skulls.
• Skull of Raxias
Obtained during The Inquisition Quest
Used in one of the demon-related mission steps.
• Skull of the Beast
Obtained during The Ice Islands Quest
Separate from “Skull of a Beast” (addon item); naming causes confusion.
• Ancient Skull
Obtained/used in The Postman Missions (late stages)
Easy to miss because it’s a transient quest item.
• Grim Reaper’s Skull
Halloween / Day of the Dead themed item
Usually obtained via seasonal content or events.
• Pumpkinhead Skull
Halloween event decoration
Distinct from pumpkins or pumpkin heads.
• Piled Skulls
Crafted/obtained via quests or special events
Not from Tibia Store, unlike Demon Skull decorations.
• Skull Candle
Found in several vampire/demon themed areas
Sometimes movable depending on server version.
These are sometimes excluded, but technically qualify:
Necromancer Skull Staff (skull embedded, monster product)
Bonelord Skull (part of Beholder/Braindeath drops, not the same as Skull item)
Werebadger Skull and Werebear Skull are listed twice (probably copy/paste).
Black Skull appears both as a drop item and as a 25 Years quest item — same name, different item IDs.
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