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Umbral master bow has 5% hit rate and bow of destruction 6%. I'm wondering if I'm using crystalline arrow with skill 100+ which one have more chance of hitting; or if both will have 100% hit chance.

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Crystalline ammo caps out at 95% hit rate from skills only, so adding 5% or more will end up with 0 misses. +5% and +6% are equally good once you have sufficient skill to cap the ammo rate (roughly 80+)
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