Rotworms used to drop Legion Helmet, but in 2009 it was removed from it and now only "Rottie the Rotworm" and "Rotworm Queen" drops it.
It is still required for an outfit (citizen)
Grynch Clan Goblin apparently once gave 1cc, Elvenhair Rope, vampire shield and some pillows, but I think it was deleted.
Well, a good call would be the old loot from Wild Warrior. Back in the day, it was possible to get a War Hammer! With 45 atk and for both hands, this was the dream of many club users back in the day. However, I remember that by 2010 the loot was already removed.
I know it's an old post, but I found it interesting. I wrote an article on that years ago, you can find it here (it's in Portuguese though): https://www.tibiabr.com/2750/2014-12-15-top-10-itens-retirados-de-loots-de-criaturas/
Some examples other than the ones already mentioned:
Dragon lance from Dragon Lord
Dragon Scale Mail from Serpent Spawn
Ornamented Axes from Wyrms
Fire Sword from Dragons
Bags from all creatures
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